@Article{PereiraMasAraGouVie:2020:CoOxSu,
author = "Pereira, Lu{\'{\i}}s Gustavo Ferroni and Maschio, Leandro
Jos{\'e} and Ara{\'u}jo, Emmanuel P{\'e}res de and Gouv{\^e}a,
Leonardo Henrique and Vieira, Ricardo",
affiliation = "{Instituto Tecnol{\'o}gico de Aeron{\'a}utica (ITA)} and
{Instituto Nacional de Pesquisas Espaciais (INPE)} and
{Universidade de S{\~a}o Paulo (USP)} and {Instituto
Tecnol{\'o}gico de Aeron{\'a}utica (ITA)} and {Instituto
Nacional de Pesquisas Espaciais (INPE)}",
title = "CoMn-spinel oxides as supported catalyst for rocket-grade hydrogen
peroxide decomposition",
journal = "Propellants, Explosives, Pyrotechnics",
year = "2020",
volume = "45",
pages = "1--8",
keywords = "Spinels, Monopropellants, Catalysts, Hydrogen peroxide, Green
propellants.",
abstract = "This work presents the application of a cobalt and manganese mixed
oxides-based catalyst with spinel structure to the decomposition
of the storable green monopropellant H(2)O(2)90 wt%. The 5.4 %
Co0.5Mn2.5O4/Al(2)O(3)catalyst was tested in a series of
continuous and pulsed 2 N thruster firings, yielding a fast and
repetitive performance, spontaneously and completely decomposing
H(2)O(2)90 wt% without undergoing deactivation or fragmentation
during the tests. A specific impulse of 104 s and a characteristic
velocity of 881 m/s were reached, so that the characteristic
velocity efficiency amounted to 93.7 %. The adiabatic
decomposition temperature of the monopropellant (756 degrees C)
was also reached, thus evidencing the effectiveness of the 5.4 %
Co0.5Mn2.5O4/Al(2)O(3)catalyst. Its excellent activity in the
decomposition of H(2)O(2)90 wt% was attributed to the presence of
the redox pairs Mn2+/Mn(3+)and Co2+/Co3+, therefore making it a
feasible material for low and medium thrust propulsive systems.",
doi = "10.1002/prep.202000020",
url = "http://dx.doi.org/10.1002/prep.202000020",
issn = "0721-3115",
language = "en",
targetfile = "pereira_comn.pdf",
urlaccessdate = "04 maio 2024"
}